アジ化リチウムのソースを表示

{{Chembox
| ImageFile = 
| ImageSize = 
| IUPACName = lithium azide
| OtherNames = 
| Section1 = {{Chembox Identifiers
|  CASNo = 19597-69-4
|  PubChem = 4176279
|  ChemSpiderID = 79536
|  SMILES = [Li+].[N-]=[N+]=[N-]
|  InChI = InChI=1S/Li.N3/c;1-3-2/q+1;-1
  }}
| Section2 = {{Chembox Properties
|  Li=1|N=3
|  Appearance = 
|  Density = 
|  MeltingPt = 
|  BoilingPt = 
|  Solubility =
  }}
| Section3 = {{Chembox Hazards
|  MainHazards = 
|  FlashPt = 
|  Autoignition =
  }}
}}
[[File:Lithium-azide-unit-cell-3D-balls.png|right|thumb|アジ化リチウムの[[単位格子]]<ref>{{ cite journal | journal = Acta Cryst. | year = 1968 | volume = B24 | issue = 2 | month = February | pages = 262-269 | doi = 10.1107/S0567740868002062 | title = The crystal structures of lithium, sodium and strontium azides | first1 = G. E. | last1= Pringle |  first2 = D. E. | last2 = Noakes }}</ref>]]

'''アジ化リチウム'''(lithium azide)は、[[組成式]]がLiN<sub>3</sub>の[[無機化合物]]である。毒性のある不安定な物質で、熱すると[[リチウム]]と[[窒素]]に分解する。

== 合成 ==
[[アジ化ナトリウム]]と[[硝酸リチウム]]との[[複分解]]により得られる。
: <chem>NaN3\ + LiNO3 -> LiN3\ + NaNO3</chem>

アジ化ナトリウムと[[硫酸リチウム]]との反応でも得られる<ref>http://www.lambdasyn.org/synfiles/lithiumazid.htm</ref>。

: <chem>2NaN3\ + Li2SO4 -> 2 LiN3\ + Na2SO4</chem>

== 脚注 ==
<references />

== 参考文献 ==
*{{cite journal | last1 = Hofman-Bang | first1 = Niels | last2 = Bjerrum | first2 = Jannik | last3 = Gloor | first3 = U. | last4 = Magnéli | first4 = Arne | last5 = Magnéli | first5 = Arne | last6 = Pestmalis | first6 = Herbert | last7 = Åsbrink | first7 = Stig | title = Preparation of Lithium Azide | journal = Acta Chemica Scandinavica | volume = 11 | pages = 581 | year = 1957 | doi = 10.3891/acta.chem.scand.11-0581}}
*{{cite journal | last1 = Younk | first1 = Edward H. | last2 = Kunz | first2 = A. Barry | title = An ab initio investigation of the electronic structure of lithium azide (LiN<sub>3</sub>), sodium azide (NaN<sub>3</sub>), and lead azide [Pb(N<sub>3</sub>)<sub>2</sub>] | journal = International Journal of Quantum Chemistry | volume = 63 | pages = 615 | year = 1997 | doi = 10.1002/(SICI)1097-461X(1997)63:3<615::AID-QUA2>3.0.CO;2-Z}}
*{{cite journal | last1 = Gordienko | first1 = A.B. | last2 = Poplavnoi | first2 = A.S. | title = The Application of ab-initio Linear Combination  of Pseudo-Atomic-Orbital Scheme  for the Electronic Structure of Lithium Azide LiN<sub>3</sub> | journal = Physica status solidi (b) | volume = 202 | pages = 941 | year = 1997 | doi = 10.1002/1521-3951(199708)202:2<941::AID-PSSB941>3.0.CO;2-K}}
*{{cite journal | last1 = Zhu | first1 = W | last2 = Xiao | first2 = J | last3 = Xiao | first3 = H | title = Density functional theory study of the structural and optical properties of lithium azide | journal = Chemical Physics Letters | volume = 422 | pages = 117 | year = 2006 | doi = 10.1016/j.cplett.2006.02.017}}

{{リチウムの化合物}}
{{デフォルトソート:あしかりちうむ}}
[[Category:リチウム塩]]
[[Category:アジ化物]]