イソプロピルアミンのソースを表示

{{Chembox
| Name=イソプロピルアミン<br/>Isopropylamine
| Watchedfields = changed
| verifiedrevid = 443886446
| ImageFileL1 = Isopropylamine.svg
| ImageFileL1_Ref = {{chemboximage|correct|??}}
| ImageSizeL1 = 120px
| ImageNameL1 = Skeletal formula of isopropylamine
| ImageFileR1 = Isopropylamine molecule ball.png
| ImageFileR1_Ref = {{chemboximage|correct|??}}
| ImageSizeR1 = 120px
| ImageNameR1 = Ball-and-stick model of the isopropylamine molecule
| IUPACName = プロパン-2-アミン<ref>{{Cite web|title=2-propylamine - Compound Summary|url=https://pubchem.ncbi.nlm.nih.gov/compound/6363|work=PubChem Compound|publisher=National Center for Biotechnology Information|accessdate=4 May 2012|location=USA|date=16 September 2004|at=Identification and Related Records}}</ref>
| OtherNames = {{Unbulleted list|2-アミノプロパン|2-プロピルアミン|1-メチルエタンアミン|モノイソプロピルアミン|sec-プロピルアミン|MIPA}}
|Section1={{Chembox Identifiers
| CASNo = 75-31-0
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 6363
| PubChem_Ref = {{Pubchemcite|correct|Pubchem}}
| ChemSpiderID = 6123
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| UNII = P8W26T4MTD
| UNII_Ref = {{fdacite|correct|FDA}}
| EINECS = 200-860-9
| UNNumber = 1221
| KEGG = C06748
| KEGG_Ref = {{keggcite|correct|kegg}}
| MeSHName = 2-propylamine
| ChEBI = 15739
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 117080
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| RTECS = NT8400000
| Beilstein = 605259
| 3DMet = B01040
| SMILES = CC(C)N
| StdInChI = 1S/C3H9N/c1-3(2)4/h3H,4H2,1-2H3
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = JJWLVOIRVHMVIS-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
}}
|Section2={{Chembox Properties
| C = 3
| H = 9
| N = 1
| Appearance = 無色透明の液体
| Odour = アンモニア臭
| Odour threshold = 1.2[[ppm]]<ref name="tci"/>
| Density = 688 mg mL<sup>−1</sup>
| MeltingPtC = -95
| BoilingPtC = 33
| Solubility = 混和
| LogP = 0.391
| VaporPressure = 63.41 kPa (at 20&nbsp;°C)
| RefractIndex = 1.3742
}}
|Section3={{Chembox Thermochemistry
| DeltaHf = −113.0–−111.6 kJ mol<sup>−1</sup>
| DeltaHc = −2.3540–−2.3550 MJ mol<sup>−1</sup>
| Entropy = 218.32 J K<sup>−1</sup> mol<sup>−1</sup>
| HeatCapacity = 163.85 J K<sup>−1</sup> mol<sup>−1</sup>
}}
|Section4={{Chembox Hazards
| GHSPictograms = {{GHS flame}} {{GHS exclamation mark}}
| GHSSignalWord = '''DANGER'''
| HPhrases = {{H-phrases|224|315|319|335}}
| PPhrases = {{P-phrases|210|261|305+351+338}}
| EUIndex = 612-007-00-1
| EUClass = {{Hazchem F+}} {{Hazchem Xi}}
| RPhrases = {{R12}}, {{R36/37/38}}
| SPhrases = {{S2}}, {{S16}}, {{S26}}, {{S29}}
| FlashPt = −20℃
| AutoignitionPt = 402℃
| ExploLimits = 2–10.4%
| LD50 = {{Unbulleted list|380 mg kg<sup>−1</sup> <small>(dermal, rabbit)</small>|550 mg kg<sup>−1</sup> <small>(oral, rat)</small>}}
| PEL = TWA 5 ppm (12 mg/m<sup>3</sup>)<ref name=NIOSH>{{PGCH|0360}}</ref>
| IDLH = 750 ppm<ref name=NIOSH/>
| LC50 = 4,000 ppm (rat, 4 hr)<ref name=IDLH>{{cite web |url = http://www.cdc.gov/niosh/idlh/75310.html |work = Immediately Dangerous to Life and Health |publisher = National Institute for Occupational Safety and Health |date = 4 December 2014 |accessdate = 14 April 2015 |title = Isopropylamine}}</ref>
| REL = None established<ref name=NIOSH/>
| LCLo = 7000 ppm (mouse, 40 min)<ref name=IDLH/>
}}
|Section8={{Chembox Related
| Function  = アルカンアミン
| OtherFunctn = {{Unbulleted list|[[エチルアミン]]|[[プロピルアミン]]|[[1,2-ジアミノプロパン]]|[[1,3-ジアミノプロパン]]|[[イソブチルアミン]]|[[tert-ブチルアミン|''tert''-ブチルアミン]]|[[n-ブチルアミン|''n''-ブチルアミン]]|[[sec-ブチルアミン|''sec''-ブチルアミン]]|[[プトレシン]]}}
| OtherCpds = [[2-メチル-2-ニトロソプロパン]]
}}
}}
'''イソプロピルアミン'''は、化学式 C3H9N|{{Chem|C|3|H|9|N}}で表されるアルキル[[アミン]]の一種。モノイソプロピルアミン、2-アミノプロパンとも呼ばれる。

== 性質 ==
[[アンモニア]]臭があり、[[嗅覚閾値]]は1.2ppm<ref name="tci">[https://www.tcichemicals.com/JP/ja/p/I0165 イソプロピルアミン]（[[東京化成工業]]）</ref>。引火点は-20℃で、日本の[[消防法]]では危険物第4類の特殊引火物に該当する。吸湿性があり、水とは混和する。[[プロトン化]]の{{pKa}}値は10.63である<ref>H. K. Hall (1957) ''J. Am. Chem. Soc.'' '''79''' 5441.</ref>。

== 製法 ==
[[イソプロピルアルコール]]と[[アンモニア]]から、[[ニッケル]]または[[銅]]の[[触媒]]の存在下で[[アミノ化]]することにより得られる<ref>{{Cite patent | inventor1-last = Boettger | inventor1-first = Guenther | inventor2-last =  Corr | inventor2-first = Hubert | inventor3-last =  Hoffmann | inventor3-first = Herwig | inventor4-last =  Toussaint | inventor4-first = Herbert | inventor5-last =  Winderl | inventor5-first = Siegfried | assignee = BASF | title = Production of Amines from Alcohols | country-code = US | patent-number = 4014933 | publication-date = 1977-03-29}}.</ref><ref>青沼孝正、[https://doi.org/10.1246/nikkashi1898.65.11_1824 イソプロピルアルコールとアンモニアからイソプロピルアミンの合成] 工業化学雑誌 65巻 (1962) 11号 p.1824-1830, {{doi|10.1246/nikkashi1898.65.11_1824}}</ref>。
: <chem>{(CH3)2CHOH} + NH3 -> {(CH3)2CHNH2} + H2O</chem>

== 用途 ==
[[グリホサート]]や[[アトラジン]]などの[[除草剤]]、[[合成樹脂添加剤]]、[[医薬品]]、ゴム薬品、[[染料]]、[[界面活性剤]]などの中間原料となる<ref>[http://www.daicel.com/yuuki/product/index.php?act=detail&page=1&id=47 製品紹介 モノイソプロピルアミン(MIPA)]（[[ダイセル]]有機合成カンパニー）</ref>。

== 脚注 ==
{{Reflist}}

== 外部リンク ==
* [https://www.ilo.org/dyn/icsc/showcard.display?p_lang=ja&p_card_id=0908&p_version=2 国際化学物質安全性カード]

{{デフォルトソート:いそふろひるあみん}}
[[Category:アミン]]
[[Category:特殊引火物]]