窒化亜鉛のソースを表示

{{chembox
| verifiedrevid = 394907738
|   Name = 窒化亜鉛<br/>Zinc nitride
|   OtherNames =
| ImageFile=Tl2O3structure.jpg 
| Section1 = {{Chembox Identifiers
|   CASNo = 1313-49-1
  }}
| Section2 = {{Chembox Properties
|   Formula = Zn<sub>3</sub>N<sub>2</sub>
|   MolarMass = 244.15 g/mol<ref name="sangeeta"/>
|   Appearance = 灰色の粉末<ref name="sangeeta"/>
|   Density = 6.22 g/cm<sup>3</sup>, 固体<ref name="sangeeta"/>
|   Solubility = 不溶（分解）
|   MeltingPt =
|   BoilingPt =
}}
| Section3 = {{Chembox Structure
|   CrystalStruct = [[立方晶]], [[Pearson symbol|cI80]]
|   SpaceGroup = Ia-3, No. 206<ref name="sangeeta"/><ref name="partin"/>
  }}
| Section7 = {{Chembox Hazards
|   EUClass = not listed
|   NFPA-H = 1
|   NFPA-R = 1
|   NFPA-F = 0
  }}
| Section8 = {{Chembox Related
|   OtherAnions = [[硝酸亜鉛]]<br/>[[硫化亜鉛]]
|   OtherCations = [[窒化リチウム]]<br/>[[窒化鉄]]
  }}
}}

'''窒化亜鉛'''（ちっかあえん、{{Lang-en-short|Zinc nitride}}）は、[[亜鉛]]の[[窒化物]]。化学式はZn<sub>3</sub>N<sub>2</sub>。純粋なものは[[立方晶]]型の結晶構造をとる<ref name="sangeeta">
{{cite book
 | last       = Sangeeta
 | first      = D.
 | title      = Inorganic Materials Chemistry Desk Reference
 | url        = https://books.google.co.jp/books?id=bdGXyilNsGMC&pg=PA278&dq=%22Zinc+nitride%22&redir_esc=y&hl=ja
 | accessdate = 2007-09-30
 | year       = 1997
 | publisher  = [[CRC Press]]
 | location   = 
 | isbn       = 978-0-8493-8900-9
 | page      = 278}}</ref><ref name="partin">
{{cite journal
 | author     = Partin, D.E., D.J. Williams, and M. O'Keeffe
 | year       = 1997
 | title      = The Crystal Structures of Mg<sub>3</sub>N<sub>2</sub>and Zn<sub>3</sub>N<sub>2</sub>
 | journal    = Journal of Solid State Chemistry
 | volume     = 132
 | issue      = 1
 | pages      = 56–59
 | doi        = 10.1006/jssc.1997.7407
 | url        = http://www.ingentaconnect.com/content/els/00224596/1997/00000132/00000001/art97407
 | accessdate = 2007-05-03}}</ref>。[[1940年]]に、Juzaらにより初めて合成された。

== 性質 ==
窒化亜鉛は、[[亜鉛アミド]]（亜鉛ジアミン）を嫌気的環境下で200℃に加熱し、熱分解することで得られる<ref name="roscoe">
{{cite book
 | author     = [[Henry Enfield Roscoe|Roscoe, Henry Enfield]], and [[Carl Schorlemmer]]
 | origyear   = 1878
 | title      = A Treatise on Chemistry: Volume II, The Metals
 | url        = https://books.google.co.jp/books?id=-K0EAAAAYAAJ&pg=PA650&dq=%22zinc+nitride%22&redir_esc=y&hl=ja#PPA650,M1
 | accessdate = 2007-11-01
 | edition    = 4th
 | year       = 1907
 | publisher  = [[Macmillan Publishers|Macmillan]]
 | location   = [[London]]
 | pages      = 650–51}}</ref> その際、副生物として[[アンモニア]]が生じる<ref name="bloxam">
{{cite book
 | last        = Bloxam
 | first       = Charles Loudon
 | title       = Chemistry, inorganic and organic
 | url         = https://books.google.co.jp/books?id=f9StqQ8YBtwC&pg=PA380&dq=%22Zinc+nitride%22&redir_esc=y&hl=ja
 | accessdate  = 2007-10-31
 | edition     = 9th
 | year        = 1903
 | publisher   = P. Blakiston's Son & Co.
 | location    = [[Philadelphia]]
 | page       = 380}}</ref>。
: <chem>3Zn(NH2)2\ -> Zn3N2\ + 4NH3</chem>

亜鉛とアンモニアを315℃に加熱することによっても得られる。その場合には、副生物として[[水素]]が生じる<ref name="roscoe"/><ref>
{{cite book
 | last       = Lowry
 | first      = Martin Thomas
 | authorlink = Thomas Martin Lowry
 | title      = Inorganic Chemistry
 | url        = https://books.google.co.jp/books?id=umQ6AAAAMAAJ&dq=%22zinc+nitride%22&q=%22zinc+nitride%22&redir_esc=y&hl=ja
 | accessdate = 2007-11-01
 | year       = 1922
 | publisher  = [[Macmillan Publishers|Macmillan]]
 | location   = 
 | page      = 872}}</ref>。
: <chem>3Zn\ + 2NH3 -> Zn3N2\ + 3H2</chem>

窒化亜鉛は水と激しく反応し、[[酸化亜鉛]]とアンモニアを生じる<ref name="roscoe"/><ref name="bloxam"/>。
: <chem>Zn3N2\ + 3H2O -> 3ZnO\ + 2NH3</chem>

[[塩酸]]に可溶で<ref>
{{cite book
 | author     = Comey, Arthur Messinger, Dorothy A. Hahn
 | title      = A Dictionary of Chemical Solubilities: Inorganic
 | url        = https://books.google.co.jp/books?id=7L0MAAAAYAAJ&pg=PA1124&dq=%22zinc+nitride%22&redir_esc=y&hl=ja
 | accessdate = 2007-11-01
 | edition    = 2nd
 | year       = 1921
 | month      = February
 | publisher  = [[Macmillan Publishers|Macmillan]]
 | location   = [[ニューヨーク|New York]]
 | page      = 1124}}</ref>、リチウムとは電気化学的・可逆的に反応する<ref>
{{cite book
 | author     = Amatucci, G.G., and N. Pereira
 | editor     = Gholam-Abbas Nazri and Gianfranco Pistoia
 | title      = Lithium Batteries: Science and Technology
 | url        = https://books.google.co.jp/books?id=k4duxuea3eIC&pg=PA256&dq=%22zinc+nitride%22&redir_esc=y&hl=ja
 | accessdate = 2007-11-01
 | year       = 2004
 | publisher  = [[Kluwer Academic Publishers]]
 | location   = 
 | isbn       = 978-1-4020-7628-2
 | chapter    = Nitride and Silicide Negative Electrodes
 | page      = 256}}</ref>。[[窒化リチウム]]や[[窒化マグネシウム]]同様、[[融点]]は高い。<ref>
{{cite book
 | author     = Grolier Incorporated
 | title      = Academic American Encyclopedia
 | url        = https://books.google.co.jp/books?id=YgI4E7w5JI8C&dq=%22zinc+nitride%22&q=%22zinc+nitride%22&redir_esc=y&hl=ja
 | accessdate = 2007-11-01
 | year       = 1994
 | publisher  = Grolier Inc.
 | location   = [[Danbury, Connecticut]]
 | isbn       = 0717220532
 | page      = 202}}</ref>

== 用途 ==
窒化亜鉛の薄膜は可視及び近赤外領域で光透過性があり、光機能素子材料としての利用が研究されている。

== 脚注 ==
{{reflist}}

== 参考文献 ==
* {{cite journal
 | author    = Futsuhara M., Yoshioka K., and Takai O.
 | date      = 1998-06-08
 | title     = Structural, electrical and optical properties of zinc nitride thin films prepared by reactive rf magnetron sputtering
 | journal   = Thin Solid Films
 | volume    = 322
 | issue     = 1
 | pages     = 274–81
 | publisher = [[Elsevier]]
 | doi       = 10.1016/S0040-6090(97)00910-3}}
* {{cite journal
 | author    = Lyutaya, M.D., and S.A. Bakuta
 | year      = 1980
 | month     = February
 | title     = Synthesis of the nitrides of Group II elements
 | journal   = Powder Metallurgy and Metal Ceramics
 | volume    = 19
 | issue     = 2
 | pages     = 118–22
 | publisher = [[Springer Science+Business Media|Springer]]
 | doi       = 10.1007/BF00792038}}

== 外部リンク ==
*[http://www.gfschemicals.com/Search/MSDS/1526MSDS.PDF Material Safety Data Sheet from GFS Chemicals]

{{亜鉛の化合物}}
{{Chem-stub}}

{{デフォルトソート:ちつかあえん}}
[[Category:窒化物]]
[[Category:亜鉛の化合物]]