酢酸カドミウムのソースを表示

{{Chembox
| Name = 酢酸カドミウム
| ImageFile = Cadmium acetate.png
| ImageSize = 
| ImageName = 
| IUPACName = 酢酸カドミウム
| OtherNames = 
| Section1 = {{Chembox Identifiers
| SMILES = [Cd+2].[O-]C(=O)C.[O-]C(=O)C
| ChemSpiderID_Ref =  {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 10521
| PubChem = 10986
| InChI = 1/2C2H4O2.Cd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
| InChIKey = LHQLJMJLROMYRN-NUQVWONBAK
| StdInChI_Ref =  {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2C2H4O2.Cd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
| StdInChIKey_Ref =  {{stdinchicite|correct|chemspider}}
| StdInChIKey = LHQLJMJLROMYRN-UHFFFAOYSA-L
| CASNo = 543-90-8
| CASNo_Ref =  {{cascite|correct|CAS}}
| CASOther = <br />[5743-04-4] (二水和物)
| RTECS = AF7505000
| EINECS = 208-853-2
}}
| Section2 = {{Chembox Properties
| Formula = Cd(CH<sub>3</sub>COO)<sub>2</sub> (無水物)<br />Cd(CH<sub>3</sub>COO)<sub>2</sub>·2H<sub>2</sub>O (二水和物)
| MolarMass = 230.500 g/mol (無水物)<br />266.529 g/mol (二水和物)
| Appearance = 透明な結晶 (無水物)<br />白色結晶 (二水和物)
| Density = 2.341 g/cm<sup>3</sup> (無水物)<br />2.01 g/cm<sup>3</sup> (二水和物)
| Solubility = [[水]]、[[メタノール]]、[[エタノール]]に可溶(無水物)<br />水に易溶、エタノールに可溶(二水和物)
| MeltingPt = 255℃ (無水物)<br />130℃で分解 (二水和物)<ref name="hand">
{{cite book
 | last = Lide
 | first = David R.
 | year = 1998
 | title = Handbook of Chemistry and Physics
 | edition = 87
 | volume = 
 | location = Boca Raton, FL
 | publisher = CRC Press
 | isbn = 0849305942 | pages = 447}}</ref>
 | BoilingPt = 
}}
| Section3 = {{Chembox Structure
| Coordination =
| CrystalStruct = 
 }}
| Section7 = {{Chembox Hazards
| ExternalMSDS = 
| EUIndex = 
| NFPA-H = 2
| NFPA-F = 1
| NFPA-R = 0
| RPhrases = {{R20/21/22}}
| SPhrases = {{S2}} {{S22}}<ref name="rsc">
{{cite book
 | last = Gangolli
 | first = S.
 | year = 1999
 | title = The Dictionary of Substances and Their Effects
 | location = London
 | publisher = Royal Society of Chemistry
 | pages = 12-13
 | url = https://books.google.co.jp/books?id=s4YittJrOsAC&pg=PA12&dq=%22Cadmium+acetate%22&as_brr=3&ei=4tzPSbj5HYfSNPL4gasE&redir_esc=y&hl=ja
 | accessdate = 2009-03-29}}</ref>
 | FlashPt = 
 }}
| Section8 = {{Chembox Related
| OtherAnions = [[フッ化カドミウム]]<br />[[塩化カドミウム]]<br />[[臭化カドミウム]]<br />[[ヨウ化カドミウム]]
| OtherCations = [[酢酸亜鉛]]<br />[[酢酸水銀(II)]]<br />[[酢酸銀]]
 }}
}}
'''酢酸カドミウム'''（さくさんカドミウム、[[英語|英]]''Cadmium acetate''）は[[カドミウム]]の[[酢酸塩]]で、[[化学式]]Cd(CH3COO)2で表される化合物。[[無水物]]と二[[水和物]]とがある
<ref name="rsc" /><ref name="icc">
{{cite book
 | last = Patnaik
 | first = Pradyot 
 | year = 2003
 | title = Handbook of Inorganic Chemical Compounds
 | publisher = McGraw-Hill Professional
 | pages = 143-144
 | isbn = 0070494398
 | url = https://books.google.co.jp/books?id=Xqj-TTzkvTEC&pg=PA243&dq=%22Cobalt+hydroxide%22+OR+%22Cobalt(II)+hydroxide%22&as_brr=3&ei=oI_NSeKSPJWOyAT5k7HWBQ&redir_esc=y&hl=ja
 | accessdate = 2009-03-29
}}</ref>。

== 用途 ==
[[陶磁器]]の製造、電気[[めっき]]、[[染色]]、[[硫黄]]・[[セレン]]・[[テルル]]の[[分析]][[試薬]]として用いられる<ref name="icc"/>。

== 生成 ==
[[酸化カドミウム]]と[[酢酸]]、または[[硝酸カドミウム]]と[[無水酢酸]]との反応により生成する。
: <chem>CdO\ + 2 CH3COOH -> Cd(CH3COO)2\ + H2O</chem>

== 安全性 ==
日本の[[毒物及び劇物取締法|毒劇法]]では劇物に指定されている<ref name="jaish">[http://www.jaish.gr.jp/anzen/gmsds/543-90-8.html 製品安全データシート（安全衛生情報センター）]</ref>。不燃性であるが、加熱により分解し、酸化カドミウムを含む有毒ガスを生じる<ref name="nihs">[https://www.ilo.org/dyn/icsc/showcard.display?p_lang=ja&p_card_id=1075&p_version=2 国際化学物質安全性カード]</ref>。[[ラット]]に経口投与した場合の[[半数致死量]]は333mg/kg<ref name="jaish"/>で、長期的には[[腎臓]]や[[骨]]に影響を及ぼす<ref name="nihs"/>。

== 脚注 ==
{{脚注ヘルプ}}
{{reflist}}

{{カドミウムの化合物}}
{{Chem-stub}}
{{DEFAULTSORT:さくさんかとみうむ}}
[[Category:カドミウムの化合物]]
[[Category:酢酸塩]]
[[Category:配位高分子]]